Lack of deviation from Michaelis–Menten kinetics for pig heart fumarase

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Affinity chromatography of pig heart fumarase.

2-(5'-Phenylpentyl)fumaric acid was shown to be a competitive inhibitor (Ki 0.5 mM) of pig heart fumarase. After nitration of the aromatic ring, reduction to the amine and diazotization, the acid was attached via azo linkages to a Sepharose 4B-tyramine matrix. The resulting adsorbent was used for the affinity chromatography of crude fumarase, purifications of approx. 20-fold being obtained by s...

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The Preparation and Characterization of Fumarase from Swine Heart Muscle.

Detailed kinetic studies of the action of crystalline fumarase (fumarate hydratase, EC 4.2.1.2) have been made by Alberty and co-workers (2, 3). These studies have given considerable insight into the mechanism of action of the enzyme and have provided a basis for understanding one type of enzymically catalyzed hydration reaction. At present, however, little is known of those structural features...

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Pig heart fumarase really does exhibit negative kinetic co-operativity at a constant ionic strength.

The kinetics of the action of fumarase on L-malate and fumarate were investigated at constant ionic strength. This was done to evaluate reports that fumarase follows simple Michaelis-Menten kinetics. However, when pH, buffer concentration and ionic strength are all maintained at constant values, the Lineweaver-Burk plots exhibit pronounced downward curvature, characteristic of negative kinetic ...

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From Guinea Pig Heart

Effects ofATP on junctional conductance (gj) were investigated in paired ventricular myocytes isolated from guinea pig hearts. One cell of the pair was voltage-clamped with a single-patch pipette, and gj was measured after the perforation of the nonjunctional membrane of the partner cell. The current-voltage relation of gj was linear between -30 and +30 mV. The control gj at 5.0 mM ATP in 88 pa...

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Effect of Aqueous-Ethanolic Extract from Rosa damascena on Guinea Pig Isolated Heart

Objective(s) In the present study, the effects of aqueous-ethanolic extract from Rosa damascena on heart rate and contractility were examined. Materials and Methods Isolated guinea-pig hearts were perfused through aorta in a Langendorff mode. Heart rate (HR) and contractility were determined in the presence of four concentrations of the extract (0.1, 0.2, 0.4 and 1.0 mg %) and isoprenaline (...

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ژورنال

عنوان ژورنال: Biochemical Journal

سال: 1980

ISSN: 0264-6021

DOI: 10.1042/bj1890653